Electrodialytic extraction of Cr from water-washed MSWI fly ash by changing pH and redox conditions

Copyright © 2017 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 71(2018) vom: 01. Jan., Seite 215-223
1. Verfasser: Chen, Wan (VerfasserIn)
Weitere Verfasser: Kirkelund, Gunvor M, Jensen, Pernille E, Ottosen, Lisbeth M
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Chromium Electrochemical Electrokinetic remediation Fly ash Sieving Waste incineration Coal Ash Metals, Heavy Particulate Matter mehr... Solid Waste Water 059QF0KO0R Carbon 7440-44-0
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100 1 |a Chen, Wan  |e verfasserin  |4 aut 
245 1 0 |a Electrodialytic extraction of Cr from water-washed MSWI fly ash by changing pH and redox conditions 
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500 |a Date Completed 13.08.2018 
500 |a Date Revised 02.12.2018 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a Copyright © 2017 Elsevier Ltd. All rights reserved. 
520 |a Electrodialytic process offers a range of possibilities to waste management by electrodialytic separation (EDS) of heavy metals, depending on how the process is designed. Using three EDS cell setups (two two-compartment and one three-compartment) and their combinations, the extraction of Cr from municipal solid waste incineration fly ash by changing pH and redox conditions was investigated in the present work. The experiments were designed into single, two and three steps, based on the number of setups (by changing EDS cells) or effective setups (by shifting working electrode pairs) used. Prior to EDS the ash studied went through pretreatments such as water-washing and dry-sieving with a 50 µm sieve. The results showed that Cr was strongly bound in the ash, and the major fraction remained bound after the different treatments. Two/three-step treatment, which obtained the maximum Cr extraction rate of 27.5%, is an improvement on the single-step that extracted maximum 3.1%. The highest extraction was obtained due to the combined extraction of Cr(III) under low pH (accompanied with high redox) conditions and Cr(VI) under high pH (low redox) conditions subsequently. The Cr leaching from the treated ashes with acidic pH was lower than from those with alkaline pH; after the three-step treatment, Cr leaching was much lower from the coarse fraction (> 50 µm), as compared to the fine (≤ 50 µm) or the unsieved ash. As for the coarse fraction, two/three-step treatment reduced the leaching of Cr compared to the single-step in the same pH range (either acidic or alkaline) 
650 4 |a Journal Article 
650 4 |a Chromium 
650 4 |a Electrochemical 
650 4 |a Electrokinetic remediation 
650 4 |a Fly ash 
650 4 |a Sieving 
650 4 |a Waste incineration 
650 7 |a Coal Ash  |2 NLM 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Particulate Matter  |2 NLM 
650 7 |a Solid Waste  |2 NLM 
650 7 |a Water  |2 NLM 
650 7 |a 059QF0KO0R  |2 NLM 
650 7 |a Carbon  |2 NLM 
650 7 |a 7440-44-0  |2 NLM 
700 1 |a Kirkelund, Gunvor M  |e verfasserin  |4 aut 
700 1 |a Jensen, Pernille E  |e verfasserin  |4 aut 
700 1 |a Ottosen, Lisbeth M  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 71(2018) vom: 01. Jan., Seite 215-223  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:71  |g year:2018  |g day:01  |g month:01  |g pages:215-223 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2017.09.035  |3 Volltext 
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