Effects of Palladium(II) Chlorocomplex Speciation on the Controlled Interaction with a Polyaniline Film in Acid
In this study, we determined the Pd(II) chlorocomplex species that has the most favorable interaction with an electropolymerized and protonated polyaniline (PANI) film. This study was completed with the intent to use this species to electrochemically build atomic palladium clusters in the PANI matri...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 43 vom: 31. Okt., Seite 11930-11935 |
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| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
| Zusammenfassung: | In this study, we determined the Pd(II) chlorocomplex species that has the most favorable interaction with an electropolymerized and protonated polyaniline (PANI) film. This study was completed with the intent to use this species to electrochemically build atomic palladium clusters in the PANI matrix. Varying amounts of NaCl were added to a K2PdCl4/HClO4 solution to result in three species studied: PdCl2(H2O)2, PdCl3(H2O)-, and PdCl42-. UV-vis spectroscopy was used to confirm the speciation, and Raman spectroscopy, X-ray photoelectron spectroscopy, and cyclic voltammograms were used to probe the interaction between the Pd species and PANI. It was determined that PdCl3(H2O)- most effectively interacts with PANI as a result of the charge balance between the anion and the protonated nitrogen-containing groups in the polymer. It has been also found that some fraction of inserted Pd(II) cannot be reduced to Pd(0) |
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| Beschreibung: | Date Completed 31.07.2018 Date Revised 31.07.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.7b02526 |