Alkane Coiling in Perfluoroalkane Solutions : A New Primitive Solvophobic Effect
In this work, we demonstrate that n-alkanes coil when mixed with perfluoroalkanes, changing their conformational equilibria to more globular states, with a higher number of gauche conformations. The new coiling effect is here observed in fluids governed exclusively by dispersion interactions, contra...
Ausführliche Beschreibung
Bibliographische Detailangaben
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 42 vom: 24. Okt., Seite 11429-11435
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| 1. Verfasser: |
Morgado, Pedro
(VerfasserIn) |
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| Weitere Verfasser: |
Garcia, Ana Rosa,
Martins, Luís F G,
Ilharco, Laura M,
Filipe, Eduardo J M |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids
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| Schlagworte: | Journal Article
Research Support, Non-U.S. Gov't |
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