|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM275633284 |
| 003 |
DE-627 |
| 005 |
20231225010128.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2017 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201701077
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0918.xml
|
| 035 |
|
|
|a (DE-627)NLM275633284
|
| 035 |
|
|
|a (NLM)28892279
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Yadav, Pankaj
|e verfasserin
|4 aut
|
| 245 |
1 |
4 |
|a The Role of Rubidium in Multiple-Cation-Based High-Efficiency Perovskite Solar Cells
|
| 264 |
|
1 |
|c 2017
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 18.07.2018
|
| 500 |
|
|
|a Date Revised 01.10.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Perovskite solar cells (PSCs) based on cesium (Cs)- and rubidium (Rb)-containing perovskite films show highly reproducible performance; however, a fundamental understanding of these systems is still emerging. Herein, this study has systematically investigated the role of Cs and Rb cations in complete devices by examining the transport and recombination processes using current-voltage characteristics and impedance spectroscopy in the dark. As the credibility of these measurements depends on the performance of devices, this study has chosen two different PSCs, (MAFACs)Pb(IBr)3 (MA = CH3 NH3+ , FA = CH(NH2 )2+ ) and (MAFACsRb)Pb(IBr)3 , yielding impressive performances of 19.5% and 21.1%, respectively. From detailed studies, this study surmises that the confluence of the low trap-assisted charge-carrier recombination, low resistance offered to holes at the perovskite/2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamine)-9,9-spirobifluorene interface with a low series resistance (Rs ), and low capacitance leads to the realization of higher performance when an extra Rb cation is incorporated into the absorber films. This study provides a thorough understanding of the impact of inorganic cations on the properties and performance of highly efficient devices, and also highlights new strategies to fabricate efficient multiple-cation-based PSCs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a charge-carrier recombination
|
| 650 |
|
4 |
|a impedance spectroscopy
|
| 650 |
|
4 |
|a interfacial properties
|
| 650 |
|
4 |
|a perovskite solar cells
|
| 700 |
1 |
|
|a Dar, M Ibrahim
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Arora, Neha
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Alharbi, Essa A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Giordano, Fabrizio
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zakeeruddin, Shaik Mohammed
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Grätzel, Michael
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 40 vom: 09. Okt.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:29
|g year:2017
|g number:40
|g day:09
|g month:10
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201701077
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 29
|j 2017
|e 40
|b 09
|c 10
|