A Simple Method for Synthesis of High-Quality Millimeter-Scale 1T' Transition-Metal Telluride and Near-Field Nanooptical Properties

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 38 vom: 04. Okt.
1. Verfasser: Chen, Kun (VerfasserIn)
Weitere Verfasser: Chen, Zefeng, Wan, Xi, Zheng, Zebo, Xie, Fangyan, Chen, Wenjun, Gui, Xuchun, Chen, Huanjun, Xie, Weiguang, Xu, Jianbin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 1T′ MoTe2 1T′ WTe2 APCVD ordinary salt promoters sub-wavelength effect
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520 |a The controlled synthesis of MoTe2 and WTe2 is crucial for their fundamental research and potential electronic applications. Here, a simplified ambient-pressure chemical vapor deposition (CVD) strategy is developed to synthesize high-quality and large-scale monolayer and few-layer 1T'-phase MoTe2 (length ≈ 1 mm) and WTe2 (length ≈ 350 µm) crystals by using ordinary salts (KCl or NaCl) as the growth promoter combining with low-cost (NH4 )6 Mo7 O24 ·4H2 O and hydrate (NH4 )10 W12 O41 ·xH2 O as the Mo and W sources, respectively. Atomic force microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and transmission electron microscopy confirm the high-quality nature and the atomic structure of the as-grown 1T' MoTe2 and WTe2 flakes. Variable-temperature transport measurements exhibit their semimetal properties. Furthermore, near-field nanooptical imaging studies are performed on the 1T' MoTe2 and WTe2 flakes for the first time. The sub-wavelength effects of 1T'-phase MoTe2 (λp ≈ 140 nm) and WTe2 (λp ≈ 100 nm) are obtained. This approach paves the way for the growth of special transition-metal dichalcogenides materials and boosts the future polaritonic research of 2D telluride compounds 
650 4 |a Journal Article 
650 4 |a 1T′ MoTe2 
650 4 |a 1T′ WTe2 
650 4 |a APCVD 
650 4 |a ordinary salt promoters 
650 4 |a sub-wavelength effect 
700 1 |a Chen, Zefeng  |e verfasserin  |4 aut 
700 1 |a Wan, Xi  |e verfasserin  |4 aut 
700 1 |a Zheng, Zebo  |e verfasserin  |4 aut 
700 1 |a Xie, Fangyan  |e verfasserin  |4 aut 
700 1 |a Chen, Wenjun  |e verfasserin  |4 aut 
700 1 |a Gui, Xuchun  |e verfasserin  |4 aut 
700 1 |a Chen, Huanjun  |e verfasserin  |4 aut 
700 1 |a Xie, Weiguang  |e verfasserin  |4 aut 
700 1 |a Xu, Jianbin  |e verfasserin  |4 aut 
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773 1 8 |g volume:29  |g year:2017  |g number:38  |g day:04  |g month:10 
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