Redox-Triggered Coloration Mechanism of Electrically Tunable Colloidal Photonic Crystals

Electrically tunable colloidal photonic crystals (ETPCs) have been investigated because of several merits such as easy color tunability, no discoloration, and clear color. The coloration mechanism of ETPCs has been explained in terms of only the electric field. Herein, we report on a new mechanism:...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 36 vom: 12. Sept., Seite 9057-9065
1. Verfasser: Yang, Ho-Sung (VerfasserIn)
Weitere Verfasser: Jang, Jinhyeok, Lee, Byoung-Sun, Kang, Tae-Hyung, Park, Jong-Jin, Yu, Woong-Ryeol
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a Electrically tunable colloidal photonic crystals (ETPCs) have been investigated because of several merits such as easy color tunability, no discoloration, and clear color. The coloration mechanism of ETPCs has been explained in terms of only the electric field. Herein, we report on a new mechanism: electric field plus redox reaction. Specifically, the coloration behavior of ETPCs was investigated under electrically conductive or insulated conditions using current-voltage, cyclic voltammetry, and zeta potential measurements, as well as scanning electron microscopy. Electrophoretic movement of ETPC particles toward the positive electrode was caused by the electric field due to the particles' negative surface charge. At the positive electrode, ETPC particles lost their electrons and formed a colloidal crystal structure. Finally, an ETPC transparent tube device was constructed to demonstrate the coloration mechanism 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Jang, Jinhyeok  |e verfasserin  |4 aut 
700 1 |a Lee, Byoung-Sun  |e verfasserin  |4 aut 
700 1 |a Kang, Tae-Hyung  |e verfasserin  |4 aut 
700 1 |a Park, Jong-Jin  |e verfasserin  |4 aut 
700 1 |a Yu, Woong-Ryeol  |e verfasserin  |4 aut 
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