|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM274571005 |
| 003 |
DE-627 |
| 005 |
20231225003754.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2017 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.7b02094
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0915.xml
|
| 035 |
|
|
|a (DE-627)NLM274571005
|
| 035 |
|
|
|a (NLM)28783345
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Nishitani, Nobuhiko
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Influence of Multidirectional Interactions on Domain Size and Shape of 2-D Molecular Assemblies
|
| 264 |
|
1 |
|c 2017
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 23.07.2018
|
| 500 |
|
|
|a Date Revised 23.07.2018
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The effect of molecule-molecule interactions on the size and shape of two-dimensional (2-D) ordering domains was investigated using scanning tunneling microscopy (STM) at the liquid/solid interface. Synthesized alkoxybenzene derivatives bearing amide group tend to form very large domains of 2-D orderings (>0.25 μm2), whereas the domain size of corresponding urea derivatives was significantly small in the same condition. The quantitative analysis of the concentration dependence of surface coverage using a nucleation-elongation model suggests that the replacement of amide functionality by urea increased the equilibrium constant of the nucleation process of 2-D self-assembly, which is a key factor for the domain size at the liquid/solid interface. Interestingly, the STM observation revealed that a slight difference of molecular structure influences the shape of 2-D ordering domains, and needle-shaped domains with large aspect ratio around 10 were observed by tuning molecule-molecule intramolecular interactions in 2-D self-assembly formed at a liquid/graphite interface
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 700 |
1 |
|
|a Hirose, Takashi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Matsuda, Kenji
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 33(2017), 36 vom: 12. Sept., Seite 9151-9159
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:33
|g year:2017
|g number:36
|g day:12
|g month:09
|g pages:9151-9159
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.7b02094
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 33
|j 2017
|e 36
|b 12
|c 09
|h 9151-9159
|