Photostriction of CH3 NH3 PbBr3 Perovskite Crystals

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 35 vom: 07. Sept.
1. Verfasser: Wei, Tzu-Chiao (VerfasserIn)
Weitere Verfasser: Wang, Hsin-Ping, Li, Ting-You, Lin, Chun-Ho, Hsieh, Ying-Hui, Chu, Ying-Hao, He, Jr-Hau
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article CH3NH3PbBr3 Raman perovskites photostriction
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520 |a Organic-inorganic hybrid perovskite materials exhibit a variety of physical properties. Pronounced coupling between phonon, organic cations, and the inorganic framework suggest that these materials exhibit strong light-matter interactions. The photoinduced strain of CH3 NH3 PbBr3 is investigated using high-resolution and contactless in situ Raman spectroscopy. Under illumination, the material exhibits large blue shifts in its Raman spectra that indicate significant structural deformations (i.e., photostriction). From these shifts, the photostrictive coefficient of CH3 NH3 PbBr3 is calculated as 2.08 × 10-8 m2 W-1 at room temperature under visible light illumination. The significant photostriction of CH3 NH3 PbBr3 is attributed to a combination of the photovoltaic effect and translational symmetry loss of the molecular configuration via strong translation-rotation coupling. Unlike CH3 NH3 PbI3 , it is noted that the photostriction of CH3 NH3 PbBr3 is extremely stable, demonstrating no signs of optical decay for at least 30 d. These results suggest the potential of CH3 NH3 PbBr3 for applications in next-generation optical micro-electromechanical devices 
650 4 |a Journal Article 
650 4 |a CH3NH3PbBr3 
650 4 |a Raman 
650 4 |a perovskites 
650 4 |a photostriction 
700 1 |a Wang, Hsin-Ping  |e verfasserin  |4 aut 
700 1 |a Li, Ting-You  |e verfasserin  |4 aut 
700 1 |a Lin, Chun-Ho  |e verfasserin  |4 aut 
700 1 |a Hsieh, Ying-Hui  |e verfasserin  |4 aut 
700 1 |a Chu, Ying-Hao  |e verfasserin  |4 aut 
700 1 |a He, Jr-Hau  |e verfasserin  |4 aut 
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