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231225s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201701789
|2 doi
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|a pubmed24n0913.xml
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|a (DE-627)NLM273907786
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|a (NLM)28715093
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Wei, Tzu-Chiao
|e verfasserin
|4 aut
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|a Photostriction of CH3 NH3 PbBr3 Perovskite Crystals
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 18.07.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Organic-inorganic hybrid perovskite materials exhibit a variety of physical properties. Pronounced coupling between phonon, organic cations, and the inorganic framework suggest that these materials exhibit strong light-matter interactions. The photoinduced strain of CH3 NH3 PbBr3 is investigated using high-resolution and contactless in situ Raman spectroscopy. Under illumination, the material exhibits large blue shifts in its Raman spectra that indicate significant structural deformations (i.e., photostriction). From these shifts, the photostrictive coefficient of CH3 NH3 PbBr3 is calculated as 2.08 × 10-8 m2 W-1 at room temperature under visible light illumination. The significant photostriction of CH3 NH3 PbBr3 is attributed to a combination of the photovoltaic effect and translational symmetry loss of the molecular configuration via strong translation-rotation coupling. Unlike CH3 NH3 PbI3 , it is noted that the photostriction of CH3 NH3 PbBr3 is extremely stable, demonstrating no signs of optical decay for at least 30 d. These results suggest the potential of CH3 NH3 PbBr3 for applications in next-generation optical micro-electromechanical devices
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|a Journal Article
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|a CH3NH3PbBr3
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|a Raman
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|a perovskites
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|a photostriction
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|a Wang, Hsin-Ping
|e verfasserin
|4 aut
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|a Li, Ting-You
|e verfasserin
|4 aut
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|a Lin, Chun-Ho
|e verfasserin
|4 aut
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|a Hsieh, Ying-Hui
|e verfasserin
|4 aut
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|a Chu, Ying-Hao
|e verfasserin
|4 aut
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|a He, Jr-Hau
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 35 vom: 07. Sept.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:29
|g year:2017
|g number:35
|g day:07
|g month:09
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|u http://dx.doi.org/10.1002/adma.201701789
|3 Volltext
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