Spectroscopic and Computational Investigation of Low-Spin Mn(III) Bis(scorpionate) Complexes
Six-coordinate MnIII complexes are typically high-spin (S = 2), however, the scorpionate ligand, both in its traditional, hydridotris(pyrazolyl)borate form, Tp- and Tp*- (the latter with 3,5-dimethylpyrazole substituents) and in an aryltris(carbene)borate (i.e., N-heterocyclic carbene, NHC) form, [P...
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Bibliographische Detailangaben
| Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2016(2016), 15-16 vom: 29. Juni, Seite 2413-2423
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| 1. Verfasser: |
Colmer, Hannah E
(VerfasserIn) |
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| Weitere Verfasser: |
Margarit, Charles G,
Smith, Jeremy M,
Jackson, Timothy A,
Telser, Joshua |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2016
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| Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry
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| Schlagworte: | Journal Article
ab initio calculations
electronic structure
magnetic circular dichroism
scorpionate ligands
zero-field splitting |
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