Studies on removal of phenol sulfonic acid-syntan in aqueous medium using ozonation
The removal of phenol sulfonic acid-syntan (PSAS) in terms of chemical oxygen demand (COD) was studied at different pH, ozone and initial PSAS concentrations and the optimum condition was found to be pH 7, ozone concentration of 5.2 × 10-3 mmol/L and initial PSAS concentration of 500 mg/L. The incre...
| Veröffentlicht in: | Environmental technology. - 1998. - 39(2018), 19 vom: 09. Okt., Seite 2434-2446 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2018
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article COD EEM ozone rate constant syntan Sulfonic Acids Phenol 339NCG44TV Ozone |
| Zusammenfassung: | The removal of phenol sulfonic acid-syntan (PSAS) in terms of chemical oxygen demand (COD) was studied at different pH, ozone and initial PSAS concentrations and the optimum condition was found to be pH 7, ozone concentration of 5.2 × 10-3 mmol/L and initial PSAS concentration of 500 mg/L. The increase in BOD5/COD ratio confirmed the bio-treatability of ozonated PSAS effluent. The excitation-emission matrix intensity and Fourier transmission infra-red spectroscopy confirmed the generation of intermediate by-product during degradation of PSAS. The ozonation of PSAS was found to obey fast regime pseudo-first-order reaction with a rate constant of 3.7 × 10-9 mol-1 s-1. The mean oxidation state of carbon value between +2 and +3 confirmed that the ozonation of PSAS resulted in partial mineralization |
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| Beschreibung: | Date Completed 09.09.2019 Date Revised 09.09.2019 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2017.1355936 |