Enhancement of Cr(VI) Ion Removal Using Nanochitosan Coated on Bituminous Activated Carbon

  Bituminous activated carbon (AC) has been widely used as a sorbent for adsorption of non-polar species, but its performance for removal of ionic species such as heavy metals has not been as efficient. In this study, AC was modified with chitosan nanoparticles (CN) using facile methods of dip coati...

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Veröffentlicht in:Water environment research : a research publication of the Water Environment Federation. - 1998. - 88(2016), 11 vom: 01. Nov., Seite 2150-2158
1. Verfasser: Chooaksorn, Wanida (VerfasserIn)
Weitere Verfasser: Nitisoravut, Rachnarin, Polprasert, Chongrak, Babel, Sandhya, Laohhasurayotin, Kritapas, Kangwansupamonkon, Wiyong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Water environment research : a research publication of the Water Environment Federation
Schlagworte:Journal Article Water Pollutants, Chemical Chromium 0R0008Q3JB Charcoal 16291-96-6 chromium hexavalent ion 18540-29-9 Chitosan 9012-76-4
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520 |a   Bituminous activated carbon (AC) has been widely used as a sorbent for adsorption of non-polar species, but its performance for removal of ionic species such as heavy metals has not been as efficient. In this study, AC was modified with chitosan nanoparticles (CN) using facile methods of dip coating and wet impregnation. The CN-coated AC demonstrated an increase in Cr(VI) removal efficiency in both kinetics and adsorption capacity. The adsorption capacity of the CN-coated AC (mg/g) was more than twice that of the uncoated AC (36.36 mg/g), or pure chitosan (32.57 mg/g). The sizes of the synthesized CN (160-2,000 nm) can be controlled by varying the concentration of the chitosan/reagents used. The adsorption isotherms are better described using the Freundlich rather than the Langmuir model and are in agreement with the heterogeneity of the surfaces. Adsorption kinetics followed that of the pseudo-second-order kinetics, suggesting chemisorption as a rate limiting step 
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700 1 |a Nitisoravut, Rachnarin  |e verfasserin  |4 aut 
700 1 |a Polprasert, Chongrak  |e verfasserin  |4 aut 
700 1 |a Babel, Sandhya  |e verfasserin  |4 aut 
700 1 |a Laohhasurayotin, Kritapas  |e verfasserin  |4 aut 
700 1 |a Kangwansupamonkon, Wiyong  |e verfasserin  |4 aut 
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