3R MoS2 with Broken Inversion Symmetry : A Promising Ultrathin Nonlinear Optical Device

Bibliographische Detailangaben
Veröffentlicht in:	Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 30 vom: 18. Aug.
1. Verfasser:	Shi, Jia (VerfasserIn)
Weitere Verfasser:	Yu, Peng, Liu, Fucai, He, Peng, Wang, Rui, Qin, Liang, Zhou, Junbo, Li, Xin, Zhou, Jiadong, Sui, Xinyu, Zhang, Shuai, Zhang, Yanfeng, Zhang, Qing, Sum, Tze Chien, Qiu, Xiaohui, Liu, Zheng, Liu, Xinfeng
Format:	Online-Aufsatz
Sprache:	English
Veröffentlicht:	2017
Zugriff auf das übergeordnete Werk:	Advanced materials (Deerfield Beach, Fla.)
Schlagworte:	Journal Article broken inversion symmetry nonlinear optical (NLO) devices polarization second harmonic generation (SHG)

Beschreibung
Zusammenfassung:	© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Nonlinear 2D layered crystals provide ideal platforms for applications and fundamental studies in ultrathin nonlinear optical (NLO) devices. However, the NLO frequency conversion efficiency constrained by lattice symmetry is still limited by layer numbers of 2D crystals. In this work, 3R MoS2 with broken inversion symmetry structure are grown and proved to be excellent NLO 2D crystals from monolayer (0.65 nm) toward bulk-like (300 nm) dimension. Thickness and wavelength-dependent second harmonic generation spectra offer the selection rules of appropriate working conditions. A model comprising of bulk nonlinear contribution and interface interaction is proposed to interpret the observed nonlinear behavior. Polarization enhancement with two petals along staggered stacking direction appears in 3R MoS2 is first observed and the robust polarization of 3R MoS2 crystal is caused by the retained broken inversion symmetry. The results provide a new arena for realizing ultrathin NLO devices for 2D layered materials
Beschreibung:	Date Completed 18.07.2018 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE
ISSN:	1521-4095
DOI:	10.1002/adma.201701486