Some Theoretical and Experimental Insights on the Mechanistic Routes Leading to the Spontaneous Grafting of Gold Surfaces by Diazonium Salts

The spontaneous grafting of diazonium salts on gold may involve the carbocation obtained by heterolytic dediazonation and not necessarily the radical, as usually observed on reducing surfaces. The mechanism is addressed on the basis of DFT calculations and experiments carried out under conditions wh...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 35 vom: 05. Sept., Seite 8730-8738
Auteur principal: Berisha, Avni (Auteur)
Autres auteurs: Combellas, Catherine, Kanoufi, Frédéric, Decorse, Philippe, Oturan, Nihal, Médard, Jérôme, Seydou, Mahamadou, Maurel, François, Pinson, Jean
Format: Article en ligne
Langue:English
Publié: 2017
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article