Some Theoretical and Experimental Insights on the Mechanistic Routes Leading to the Spontaneous Grafting of Gold Surfaces by Diazonium Salts
The spontaneous grafting of diazonium salts on gold may involve the carbocation obtained by heterolytic dediazonation and not necessarily the radical, as usually observed on reducing surfaces. The mechanism is addressed on the basis of DFT calculations and experiments carried out under conditions wh...
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| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 35 vom: 05. Sept., Seite 8730-8738
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| 1. Verfasser: |
Berisha, Avni
(VerfasserIn) |
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| Weitere Verfasser: |
Combellas, Catherine,
Kanoufi, Frédéric,
Decorse, Philippe,
Oturan, Nihal,
Médard, Jérôme,
Seydou, Mahamadou,
Maurel, François,
Pinson, Jean |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids
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| Schlagworte: | Journal Article |
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