Ion Transport Mechanisms in Liquid-Liquid Interface

Interfacial liquid-liquid ion transport is of crucial importance to biotechnology and industrial separation processes including nuclear elements and rare earths. A water-in-oil microemulsion is formulated here with density and dimensions amenable to atomistic molecular dynamics simulation, facilitat...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 24 vom: 20. Juni, Seite 6135-6142
1. Verfasser: Qiao, Baofu (VerfasserIn)
Weitere Verfasser: Muntean, John V, Olvera de la Cruz, Monica, Ellis, Ross J
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.
LEADER 01000caa a22002652 4500
001 NLM272390895
003 DE-627
005 20250221174415.0
007 cr uuu---uuuuu
008 231224s2017 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.7b01230  |2 doi 
028 5 2 |a pubmed25n0907.xml 
035 |a (DE-627)NLM272390895 
035 |a (NLM)28558243 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Qiao, Baofu  |e verfasserin  |4 aut 
245 1 0 |a Ion Transport Mechanisms in Liquid-Liquid Interface 
264 1 |c 2017 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 16.07.2018 
500 |a Date Revised 16.07.2018 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Interfacial liquid-liquid ion transport is of crucial importance to biotechnology and industrial separation processes including nuclear elements and rare earths. A water-in-oil microemulsion is formulated here with density and dimensions amenable to atomistic molecular dynamics simulation, facilitating convergent theoretical and experimental approaches to elucidate interfacial ion transport mechanisms. Lutetium(III) cations are transported from the 5 nm diameter water pools into the surrounding oil using an extractant (a lipophilic ligand). Changes in ion coordination sphere and interactions between the interfacial components are studied using a combination of synchrotron X-ray scattering, spectroscopy, and atomistic molecular dynamics simulations. Contrary to existing hypotheses, our model system shows no evidence of interfacial extractant monolayers, but rather ions are exchanged through water channels that penetrate the surfactant monolayer and connect to the oil-based extractant. Our results highlight the dynamic nature of the oil-water interface and show that lipophilic ion shuttles need not form flat monolayer structures to facilitate ion transport across the liquid-liquid interface 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
700 1 |a Muntean, John V  |e verfasserin  |4 aut 
700 1 |a Olvera de la Cruz, Monica  |e verfasserin  |4 aut 
700 1 |a Ellis, Ross J  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1985  |g 33(2017), 24 vom: 20. Juni, Seite 6135-6142  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:33  |g year:2017  |g number:24  |g day:20  |g month:06  |g pages:6135-6142 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.7b01230  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 33  |j 2017  |e 24  |b 20  |c 06  |h 6135-6142