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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201605506
|2 doi
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|a pubmed24n0907.xml
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|a DE-627
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|e rakwb
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|a eng
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|a Zhang, Qiangqiang
|e verfasserin
|4 aut
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|a Flyweight, Superelastic, Electrically Conductive, and Flame-Retardant 3D Multi-Nanolayer Graphene/Ceramic Metamaterial
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 19.10.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a A ceramic/graphene metamaterial (GCM) with microstructure-derived superelasticity and structural robustness is achieved by designing hierarchical honeycomb microstructures, which are composited with two brittle constituents (graphene and ceramic) assembled in multi-nanolayer cellular walls. Attributed to the designed microstructure, well-interconnected scaffolds, chemically bonded interface, and coupled strengthening effect between the graphene framework and the nanolayers of the Al2 O3 ceramic (NAC), the GCM demonstrates a sequence of multifunctional properties simultaneously that have not been reported for ceramics and ceramics-matrix-composite structures, such as flyweight density, 80% reversible compressibility, high fatigue resistance, high electrical conductivity, and excellent thermal-insulation/flame-retardant performance simultaneously. The 3D well-ordered graphene aerogel templates are strongly coupled with the NAC by the chemically bonded interface, exhibiting mutual strengthening, compatible deformability, and a linearly dependent relationship between the density and Young's modulus. Considerable size effects of the ceramic nanolayers on the mechanical properties are revealed in these ceramic-based metamaterials. The designed hierarchical honeycomb graphene with a fourth dimensional control of the ceramic nanolayers on new ways to scalable fabrication of advanced multifunctional ceramic composites with controllable design suggest a great potential in applications of flexible conductors, shock/vibration absorbers, thermal shock barriers, thermal insulation/flame-retardant skins, and porous microwave-absorbing coatings
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|a Journal Article
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|a graphene/ceramic metamaterials
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|a in situ observations
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|a multi-nanolayers
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|a size effect
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|a superelasticity
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|a “bottom-up” processes
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|a Lin, Dong
|e verfasserin
|4 aut
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|a Deng, Biwei
|e verfasserin
|4 aut
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|a Xu, Xiang
|e verfasserin
|4 aut
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|a Nian, Qiong
|e verfasserin
|4 aut
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|a Jin, Shengyu
|e verfasserin
|4 aut
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|a Leedy, Kevin D
|e verfasserin
|4 aut
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|a Li, Hui
|e verfasserin
|4 aut
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|a Cheng, Gary J
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 28 vom: 21. Juli
|w (DE-627)NLM098206397
|x 1521-4095
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|g volume:29
|g year:2017
|g number:28
|g day:21
|g month:07
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|u http://dx.doi.org/10.1002/adma.201605506
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