Structure and Rheology of Wormlike Micelles Formed by Fluorocarbon-Hydrocarbon-Type Hybrid Gemini Surfactant in Aqueous Solution
The structure and rheological properties of wormlike micelles formed by a fluorocarbon-hydrocarbon-type hybrid gemini surfactant in an aqueous solution were investigated by means of small-angle X-ray scattering (SAXS) and viscoelastic measurements. The cross-sectional structure (the radius of the hy...
| Publié dans: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 24 vom: 20. Juni, Seite 6084-6091 |
|---|---|
| Auteur principal: | |
| Autres auteurs: | , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2017
|
| Accès à la collection: | Langmuir : the ACS journal of surfaces and colloids |
| Sujets: | Journal Article Research Support, Non-U.S. Gov't |
| Résumé: | The structure and rheological properties of wormlike micelles formed by a fluorocarbon-hydrocarbon-type hybrid gemini surfactant in an aqueous solution were investigated by means of small-angle X-ray scattering (SAXS) and viscoelastic measurements. The cross-sectional structure (the radius of the hydrophobic core and the thickness of the hydrophilic shell) and the aggregation number per unit axial length of wormlike micelles were evaluated by a model fitting analysis of SAXS profiles. Both parameters for the hybrid gemini surfactant were smaller than those of a corresponding hydrocarbon-hydrocarbon-type gemini surfactant. On the other hand, the viscosity of the hybrid gemini surfactant was higher than that of the hydrocarbon-hydrocarbon-type gemini surfactant. From the viscoelastic parameters, the steady state compliance, Je, and the terminal relaxation time, τw, which were independently obtained by dynamic viscoelastic measurement, we revealed that a larger number of entanglements and a longer contour length of the hybrid gemini surfactant led to the higher viscosity. These results obtained by the rheological measurements were consistent with those obtained by SAXS analysis |
|---|---|
| Description: | Date Completed 16.07.2018 Date Revised 16.07.2018 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.7b00902 |