|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM271943246 |
| 003 |
DE-627 |
| 005 |
20231224233817.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2017 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.7b00591
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0906.xml
|
| 035 |
|
|
|a (DE-627)NLM271943246
|
| 035 |
|
|
|a (NLM)28509560
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Alizadeh, Shima
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Multiscale Model for Electrokinetic Transport in Networks of Pores, Part II
|b Computational Algorithms and Applications
|
| 264 |
|
1 |
|c 2017
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 16.07.2018
|
| 500 |
|
|
|a Date Revised 16.07.2018
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The first part of this two-article series presented a robust mathematical model for the fast and accurate prediction of electrokinetic phenomena in porous networks with complex topologies. In the second part of this series, we first present a numerical algorithm that can efficiently solve the model equations. We then demonstrate that the resulting framework is capable of capturing a wide range of transport phenomena in microstructures by considering a hierarchy of canonical problems with increasing complexity. The developed framework is validated against direct numerical simulations of deionization shocks in micropore-membrane junctions and concentration polarization in micro- and nanochannel systems. We demonstrate that for thin pores subject to concentration gradients our model consistently captures correct induced osmotic pressure, which is a macroscopic phenomena originally derived from thermodynamic principles but here is naturally predicted through microscopic electrostatic interactions. Moreover, we show that the developed model captures current rectification phenomena in a conical nanopore subject to an axial external electric field. Finally, we provide discussions on examples involving stationary and moving deionization shocks in micropore nanopore T-junctions as well as induced-flow loops when pores of varying sizes are connected in parallel
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, U.S. Gov't, Non-P.H.S.
|
| 700 |
1 |
|
|a Mani, Ali
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 33(2017), 25 vom: 27. Juni, Seite 6220-6231
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:33
|g year:2017
|g number:25
|g day:27
|g month:06
|g pages:6220-6231
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.7b00591
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 33
|j 2017
|e 25
|b 27
|c 06
|h 6220-6231
|