Recycling of spent lithium-ion battery with polyvinyl chloride by mechanochemical process
Copyright © 2017. Published by Elsevier Ltd.
| Veröffentlicht in: | Waste management (New York, N.Y.). - 1999. - 67(2017) vom: 15. Sept., Seite 232-239 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Waste management (New York, N.Y.) |
| Schlagworte: | Journal Article Cobalt ferrite Lithium recovery Mechanochemical method Spent lithium-ion batteries Waste polyvinyl chloride Metals Polyvinyl Chloride 9002-86-2 Lithium |
| Zusammenfassung: | Copyright © 2017. Published by Elsevier Ltd. In the present study, cathode materials (C/LiCoO2) of spent lithium-ion batteries (LIBs) and waste polyvinyl chloride (PVC) were co-processed via an innovative mechanochemical method, i.e. LiCoO2/PVC/Fe was co-grinded followed by water-leaching. This procedure generated recoverable LiCl from Li by the dechlorination of PVC and also generated magnetic CoFe4O6 from Co. The effects of different additives (e.g. alkali metals, non-metal oxides, and zero-valent metals) on (i) the conversion rates of Li and Co and (ii) the dechlorination rate of PVC were investigated, and the reaction mechanisms were explored. It was found that the chlorine atoms in PVC were mechanochemically transformed into chloride ions that bound to the Li in LiCoO2 to form LiCl. This resulted in reorganization of the Co and Fe crystals to form the magnetic material CoFe4O6. This study provides a more environmentally-friendly, economical, and straightforward approach for the recycling of spent LIBs and waste PVC compared to traditional processes |
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| Beschreibung: | Date Completed 17.01.2018 Date Revised 02.12.2018 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1879-2456 |
| DOI: | 10.1016/j.wasman.2017.05.013 |