Optochemically Responsive 2D Nanosheets of a 3D Metal-Organic Framework Material
© 2017 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 27 vom: 15. Juli |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article host-guest interactions hybrid materials metal-organic framework (MOF) nanosheets photochemical sensors |
| Zusammenfassung: | © 2017 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Outstanding functional tunability underpinning metal-organic framework (MOF) confers a versatile platform to contrive next-generation chemical sensors, optoelectronics, energy harvesters, and converters. A rare exemplar of a porous 2D nanosheet material constructed from an extended 3D MOF structure is reported. A rapid supramolecular self-assembly methodology at ambient conditions to synthesize readily exfoliatable MOF nanosheets, functionalized in situ by adopting the guestMOF (host) strategy, is developed. Nanoscale confinement of light-emitting molecules (as functional guest) inside the MOF pores generates unusual combination of optical, electronic, and chemical properties, arising from the strong host-guest coupling effects. Highly promising photonics-based chemical sensing opened up by the new guest@MOF composite systems is shown. By harnessing host-guest optochemical interactions of functionalized MOF nanosheets, detection of an extensive range of volatile organic compounds and small molecules important for many practical applications has been accomplished |
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| Beschreibung: | Date Completed 18.07.2018 Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201701463 |