Ion Exchange Thermodynamics at the Rutile-Water Interface : Flow Microcalorimetric Measurements and Surface Complexation Modeling of Na-K-Rb-Cl-NO3 Adsorption
Flow microcalorimetry was used to investigate the energetics associated with Rb+, K+, Na+, Cl-, and NO3- exchange at the rutile-water interface. Heats of exchange reflected differences in bulk hydration/dehydration enthalpies (Na+ > K+ > Rb+, and Cl- > NO3-) such that exchanging Na+ or Cl-...
Ausführliche Beschreibung
Bibliographische Detailangaben
Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 20 vom: 23. Mai, Seite 4934-4941
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1. Verfasser: |
Hawkins, Tyler
(VerfasserIn) |
Weitere Verfasser: |
Allen, Nicholas,
Machesky, Michael L,
Wesolowski, David J,
Kabengi, Nadine |
Format: | Online-Aufsatz
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Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids
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Schlagworte: | Journal Article
Research Support, U.S. Gov't, Non-P.H.S. |