300% Enhancement of Carrier Mobility in Uniaxial-Oriented Perovskite Films Formed by Topotactic-Oriented Attachment

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 23 vom: 20. Juni
1. Verfasser: Kim, Dong Hoe (VerfasserIn)
Weitere Verfasser: Park, Jaehong, Li, Zhen, Yang, Mengjin, Park, Ji-Sang, Park, Ik Jae, Kim, Jin Young, Berry, Joseph J, Rumbles, Garry, Zhu, Kai
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article carrier mobility orientation perovskite films solar cells topotactic-oriented attachment
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520 |a Organic-inorganic perovskites with intriguing optical and electrical properties have attracted significant research interests due to their excellent performance in optoelectronic devices. Recent efforts on preparing uniform and large-grain polycrystalline perovskite films have led to enhanced carrier lifetime up to several microseconds. However, the mobility and trap densities of polycrystalline perovskite films are still significantly behind their single-crystal counterparts. Here, a facile topotactic-oriented attachment (TOA) process to grow highly oriented perovskite films, featuring strong uniaxial-crystallographic texture, micrometer-grain morphology, high crystallinity, low trap density (≈4 × 1014 cm-3 ), and unprecedented 9 GHz charge-carrier mobility (71 cm2 V-1 s-1 ), is demonstrated. TOA-perovskite-based n-i-p planar solar cells show minimal discrepancies between stabilized efficiency (19.0%) and reverse-scan efficiency (19.7%). The TOA process is also applicable for growing other state-of-the-art perovskite alloys, including triple-cation and mixed-halide perovskites 
650 4 |a Journal Article 
650 4 |a carrier mobility 
650 4 |a orientation 
650 4 |a perovskite films 
650 4 |a solar cells 
650 4 |a topotactic-oriented attachment 
700 1 |a Park, Jaehong  |e verfasserin  |4 aut 
700 1 |a Li, Zhen  |e verfasserin  |4 aut 
700 1 |a Yang, Mengjin  |e verfasserin  |4 aut 
700 1 |a Park, Ji-Sang  |e verfasserin  |4 aut 
700 1 |a Park, Ik Jae  |e verfasserin  |4 aut 
700 1 |a Kim, Jin Young  |e verfasserin  |4 aut 
700 1 |a Berry, Joseph J  |e verfasserin  |4 aut 
700 1 |a Rumbles, Garry  |e verfasserin  |4 aut 
700 1 |a Zhu, Kai  |e verfasserin  |4 aut 
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773 1 8 |g volume:29  |g year:2017  |g number:23  |g day:20  |g month:06 
856 4 0 |u http://dx.doi.org/10.1002/adma.201606831  |3 Volltext 
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