Ferrrate(VI) and freeze-thaw treatment for oxidation of hormones and inactivation of fecal coliforms in sludge

This study examined the individual and combined effects of potassium ferrate(VI) additions and freeze-thaw conditioning for the treatment and dewatering of wastewater sludge in cold climates, with particular focus on the inactivation of fecal coliforms and oxidation of estrogens, androgens, and prog...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 75(2017), 7-8 vom: 19. Apr., Seite 1625-1632
1. Verfasser: Diak, James (VerfasserIn)
Weitere Verfasser: Örmeci, Banu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Estrogens Hormones Iron Compounds Potassium Compounds Sewage Waste Water Estrone 2DI9HA706A potassium ferrate mehr... 39469-86-8 Ethinyl Estradiol 423D2T571U Estradiol 4TI98Z838E
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520 |a This study examined the individual and combined effects of potassium ferrate(VI) additions and freeze-thaw conditioning for the treatment and dewatering of wastewater sludge in cold climates, with particular focus on the inactivation of fecal coliforms and oxidation of estrogens, androgens, and progestogens. The first phase of the study evaluated the effects of potassium ferrate(VI) pre-treatment followed by freeze-thaw at -20 °C using a low (0.5 g/L) and high (5.0 g/L) dose of potassium ferrate(VI). The results showed that pre-treatment of anaerobically digested sludge with 5 g/L of potassium ferrate(VI) reduced the concentration of fecal coliforms in the sludge cake to below 100 MPN/g DS. The second phase evaluated the ability of ferrate(VI) to oxidise selected hormones in sludge. Anaerobically digested sludge samples were spiked with 10 different hormones: estrone (E1), 17α-estradiol, 17β-estradiol (E2), estriol (E3), 17α-ethinylestradiol (EE2), equilin, mestranol, testosterone, norethindrone and norgestrel in two groups of low (3-75 ng/mL) and high (12-300 ng/L) concentration ranges of hormones. The samples were treated with either 0.5 or 1.0 g/L of potassium ferrate(VI), and hormone concentrations were measured again after treatment. Potassium ferrate(VI) additions as low as 1.0 g/L reduced the concentration of estrogens in sludge. Potassium ferrate(VI) additions of 0.5 and 1.0 g/L were less effective at reducing the concentrations of androgens and progestogens. Increasing ferrate(VI) dose would likely result in more substantial decreases in the concentrations of fecal coliforms and hormones. The results of this study indicate that the combined use of freeze-thaw and ferrate(VI) has the potential to provide a complete sludge treatment solution in cold regions 
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650 7 |a Estrogens  |2 NLM 
650 7 |a Hormones  |2 NLM 
650 7 |a Iron Compounds  |2 NLM 
650 7 |a Potassium Compounds  |2 NLM 
650 7 |a Sewage  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Estrone  |2 NLM 
650 7 |a 2DI9HA706A  |2 NLM 
650 7 |a potassium ferrate  |2 NLM 
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650 7 |a Estradiol  |2 NLM 
650 7 |a 4TI98Z838E  |2 NLM 
700 1 |a Örmeci, Banu  |e verfasserin  |4 aut 
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