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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.7b00206
|2 doi
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|a eng
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1 |
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|a Kleinerman, Olga
|e verfasserin
|4 aut
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| 245 |
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|a Direct Imaging of Carbon Nanotube Liquid-Crystalline Phase Development in True Solutions
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|c 2017
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|a Text
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|a ƒaComputermedien
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|a Date Completed 09.07.2018
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|a Date Revised 09.07.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Using direct-imaging cryogenic transmission and scanning electron microscopy, we show different stages of liquid-crystalline phase development in progressively more concentrated solutions of carbon nanotubes in chlorosulfonic acid: a dilute phase of individually dissolved carbon nanotubes; semidilute and concentrated isotropic phases; coexisting concentrated isotropic and nematic phases in local equilibrium with each other; and a fully liquid-crystalline phase. Nanometric resolution of cryogenic electron microscopy reveals carbon nanotube self-assembly into liquid-crystalline domains of several nanometers in width at very early stages. We find significant differences in carbon nanotube liquid-crystalline domain morphology as a function of the carbon nanotube aspect ratio, diameter, and degree of purity
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Liberman, Lucy
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Behabtu, Natnael
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Pasquali, Matteo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cohen, Yachin
|e verfasserin
|4 aut
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| 700 |
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|a Talmon, Yeshayahu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 33(2017), 16 vom: 25. Apr., Seite 4011-4018
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|g year:2017
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|g day:25
|g month:04
|g pages:4011-4018
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|u http://dx.doi.org/10.1021/acs.langmuir.7b00206
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