Investigation of the compatibility of xanthan gum (XG) and calcium polysulfide and the rheological properties of XG solutions

Shear thinning xanthan gum (XG) solutions as the delivery media can solve the bypassing problem induced by heterogeneity, especially with low permeable zones in aquifers. Experiments were conducted to investigate the compatibility of XG and calcium polysulfide (CPS) aiming at chromium contamination...

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Veröffentlicht in:Environmental technology. - 1993. - 39(2018), 5 vom: 01. März, Seite 607-615
1. Verfasser: Liu, Dengfeng (VerfasserIn)
Weitere Verfasser: Ren, Liming, Wen, Chunyu, Dong, Jun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Xanthan gum calcium polysulfide groundwater hexavalent chromium viscosity Calcium Compounds Polysaccharides, Bacterial Sulfides Water Pollutants, Chemical mehr... calcium sulfide 1MBW07J51Q xanthan gum TTV12P4NEE
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520 |a Shear thinning xanthan gum (XG) solutions as the delivery media can solve the bypassing problem induced by heterogeneity, especially with low permeable zones in aquifers. Experiments were conducted to investigate the compatibility of XG and calcium polysulfide (CPS) aiming at chromium contamination in groundwater. Rheological properties of XG solutions DURING delivery were studied. Results indicated that (1) XG slowed down the reduction of hexavalent chromium by CPS, and the reaction fitted well with the second-order kinetics. (2) CPS dosage had a significant effect on the removal of chromium (VI), but it was less pronounced as the CPS concentration over 160 mg/L. (3) Cationic ions (e.g. Na+ and Ca2+) decreased the solution viscosity, while anionic ions maintained the viscosity and shear thinning properties of XG solutions. CPS decreased the viscosity of XG solutions. (4) The solution viscosity increased linearly with the XG concentration (less than 1500 mg/L) at a low shear rate. The presence of aquifer media resulted in a drastic decrease in solution viscosity due to physical molecular breakdown and biodegradation. (5) The rheological properties of XG solutions were described by a power law model. The presented empirical relations may also provide a theoretical basis for field applications 
650 4 |a Journal Article 
650 4 |a Xanthan gum 
650 4 |a calcium polysulfide 
650 4 |a groundwater 
650 4 |a hexavalent chromium 
650 4 |a viscosity 
650 7 |a Calcium Compounds  |2 NLM 
650 7 |a Polysaccharides, Bacterial  |2 NLM 
650 7 |a Sulfides  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a calcium sulfide  |2 NLM 
650 7 |a 1MBW07J51Q  |2 NLM 
650 7 |a xanthan gum  |2 NLM 
650 7 |a TTV12P4NEE  |2 NLM 
700 1 |a Ren, Liming  |e verfasserin  |4 aut 
700 1 |a Wen, Chunyu  |e verfasserin  |4 aut 
700 1 |a Dong, Jun  |e verfasserin  |4 aut 
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773 1 8 |g volume:39  |g year:2018  |g number:5  |g day:01  |g month:03  |g pages:607-615 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2017.1309073  |3 Volltext 
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