Light Control of Charge Transfer and Excitonic Transitions in a Carbon Nanotube/Porphyrin Hybrid

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 18 vom: 17. Mai
1. Verfasser: Chen, Yani (VerfasserIn)
Weitere Verfasser: Royal, Guy, Flahaut, Emmanuel, Cobo, Saioa, Bouchiat, Vincent, Marty, Laëtitia, Bendiab, Nedjma
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Raman enhancement nanotubes optoelectronics porphyrins single electron tunneling
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520 |a Carbon nanotube-chromophore hybrids are promising building blocks in order to obtain a controlled electro-optical transduction effect at the single nano-object level. In this work, a strong spectral selectivity of the electronic and the phononic response of a chromophore-coated single nanotube transistor is observed for which standard photogating cannot account. This paper investigates how light irradiation strongly modifies the coupling between molecules and nanotube within the hybrid by means of combined Raman diffusion and electron transport measurements. Moreover, a nonconventional Raman enhancement effect is observed when light irradiation is on the absorption range of the grafted molecule. Finally, this paper shows how the dynamics of single electron tunneling in the device at low temperature is strongly modified by molecular photoexcitation. Both effects will be discussed in terms of photoinduced excitons coupled to electronic levels 
650 4 |a Journal Article 
650 4 |a Raman enhancement 
650 4 |a nanotubes 
650 4 |a optoelectronics 
650 4 |a porphyrins 
650 4 |a single electron tunneling 
700 1 |a Royal, Guy  |e verfasserin  |4 aut 
700 1 |a Flahaut, Emmanuel  |e verfasserin  |4 aut 
700 1 |a Cobo, Saioa  |e verfasserin  |4 aut 
700 1 |a Bouchiat, Vincent  |e verfasserin  |4 aut 
700 1 |a Marty, Laëtitia  |e verfasserin  |4 aut 
700 1 |a Bendiab, Nedjma  |e verfasserin  |4 aut 
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