Ag2S/Ag Heterostructure : A Promising Electrocatalyst for the Hydrogen Evolution Reaction

Different metal chalcogenides, being a potential candidate for hydrogen evolution catalysts, have attracted enormous attention in the field of water splitting. In the present study, Ag2S/Ag is revealed as an efficient catalyst for hydrogen evolution. When a sacrificial template of the CuS nanostruct...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 33(2017), 13 vom: 04. Apr., Seite 3178-3186
1. Verfasser: Basu, Mrinmoyee (VerfasserIn)
Weitere Verfasser: Nazir, Roshan, Mahala, Chavi, Fageria, Pragati, Chaudhary, Sumita, Gangopadhyay, Subhashis, Pande, Surojit
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a Different metal chalcogenides, being a potential candidate for hydrogen evolution catalysts, have attracted enormous attention in the field of water splitting. In the present study, Ag2S/Ag is revealed as an efficient catalyst for hydrogen evolution. When a sacrificial template of the CuS nanostructure is used, Ag2S/Ag heterostructures are synthesized following a simple wet-chemical technique. Two different routes, wet chemical and hydrothermal, are followed to modulate the morphology of the CuS templates from flower ball to wirelike structures, which subsequently results in the formation of Ag2S nanostructure. Finally, the Ag layer is deposited on Ag2S with the help of a photoreduction technique. The unique heterostructure of Ag2S/Ag shows efficient catalytic activity in the H2 evolution reaction. A Ag2S/Ag wire can successfully generate a 10 mA/cm2 current density at a -0.199 V potential. Ag2S/Ag contains the micronanostructure where nanoplates of Ag2S/Ag assemble to give rise to microstructures such as flower balls and wire 
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700 1 |a Nazir, Roshan  |e verfasserin  |4 aut 
700 1 |a Mahala, Chavi  |e verfasserin  |4 aut 
700 1 |a Fageria, Pragati  |e verfasserin  |4 aut 
700 1 |a Chaudhary, Sumita  |e verfasserin  |4 aut 
700 1 |a Gangopadhyay, Subhashis  |e verfasserin  |4 aut 
700 1 |a Pande, Surojit  |e verfasserin  |4 aut 
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