Removal of ammonium from municipal wastewater with powdered and granulated metakaolin geopolymer

Ammonium [Formula: see text] removal from municipal wastewater poses challenges with the commonly used biological processes. Especially at low wastewater temperatures, the process is frequently ineffective and difficult to control. One alternative is to use ion-exchange. In the present study, a nove...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Environmental technology. - 1993. - 39(2018), 4 vom: 02. Feb., Seite 414-423
1. Verfasser: Luukkonen, Tero (VerfasserIn)
Weitere Verfasser: Věžníková, Kateřina, Tolonen, Emma-Tuulia, Runtti, Hanna, Yliniemi, Juho, Hu, Tao, Kemppainen, Kimmo, Lassi, Ulla
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Alkali activation ammonium geopolymer ion exchange municipal wastewater Ammonium Compounds Polymers Waste Water Water Pollutants, Chemical mehr... Kaolin 24H4NWX5CO
LEADER 01000caa a22002652c 4500
001 NLM269692029
003 DE-627
005 20250221082200.0
007 cr uuu---uuuuu
008 231224s2018 xx |||||o 00| ||eng c
024 7 |a 10.1080/09593330.2017.1301572  |2 doi 
028 5 2 |a pubmed25n0898.xml 
035 |a (DE-627)NLM269692029 
035 |a (NLM)28278098 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Luukkonen, Tero  |e verfasserin  |4 aut 
245 1 0 |a Removal of ammonium from municipal wastewater with powdered and granulated metakaolin geopolymer 
264 1 |c 2018 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 19.01.2018 
500 |a Date Revised 07.12.2022 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a Ammonium [Formula: see text] removal from municipal wastewater poses challenges with the commonly used biological processes. Especially at low wastewater temperatures, the process is frequently ineffective and difficult to control. One alternative is to use ion-exchange. In the present study, a novel [Formula: see text] ion-exchanger, metakaolin geopolymer (MK-GP), was prepared, characterised, and tested. Batch experiments with powdered MK-GP indicated that the maximum exchange capacities were 31.79, 28.77, and 17.75 mg/g in synthetic, screened, and pre-sedimented municipal wastewater, respectively, according to the Sips isotherm (R2 ≥ 0.91). Kinetics followed the pseudo-second-order rate equation in all cases (kp2 = 0.04-0.24 g mg-1 min-1, R2 ≥ 0.97) and the equilibrium was reached within 30-90 min. Granulated MK-GP proved to be suitable for a continuous column mode use. Granules were high-strength, porous at the surface and could be regenerated multiple times with NaCl/NaOH. A bench-scale pilot test further confirmed the feasibility of granulated MK-GP in practical conditions at a municipal wastewater treatment plant: consistently <4 mg/L [Formula: see text] could be reached even though wastewater had low temperature (approx. 10°C). The results indicate that powdered or granulated MK-GP might have practical potential for removal and possible recovery of [Formula: see text] from municipal wastewaters. The simple and low-energy preparation method for MK-GP further increases the significance of the results 
650 4 |a Journal Article 
650 4 |a Alkali activation 
650 4 |a ammonium 
650 4 |a geopolymer 
650 4 |a ion exchange 
650 4 |a municipal wastewater 
650 7 |a Ammonium Compounds  |2 NLM 
650 7 |a Polymers  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Kaolin  |2 NLM 
650 7 |a 24H4NWX5CO  |2 NLM 
700 1 |a Věžníková, Kateřina  |e verfasserin  |4 aut 
700 1 |a Tolonen, Emma-Tuulia  |e verfasserin  |4 aut 
700 1 |a Runtti, Hanna  |e verfasserin  |4 aut 
700 1 |a Yliniemi, Juho  |e verfasserin  |4 aut 
700 1 |a Hu, Tao  |e verfasserin  |4 aut 
700 1 |a Kemppainen, Kimmo  |e verfasserin  |4 aut 
700 1 |a Lassi, Ulla  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 39(2018), 4 vom: 02. Feb., Seite 414-423  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnas 
773 1 8 |g volume:39  |g year:2018  |g number:4  |g day:02  |g month:02  |g pages:414-423 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2017.1301572  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 39  |j 2018  |e 4  |b 02  |c 02  |h 414-423