Biopolymer-Targeted Adsorption onto Halloysite Nanotubes in Aqueous Media

Studies on the adsorption of biopolymers onto halloysite nanotubes (HNTs) in water were conducted. Three polymers with different charges-anionic (pectin), neutral (hydroxypropyl cellulose), and cationic (chitosan)-were chosen. The thermodynamic parameters for the adsorption of polymers onto the HNT...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 13 vom: 04. Apr., Seite 3317-3323
1. Verfasser: Bertolino, Vanessa (VerfasserIn)
Weitere Verfasser: Cavallaro, Giuseppe, Lazzara, Giuseppe, Milioto, Stefana, Parisi, Filippo
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a Studies on the adsorption of biopolymers onto halloysite nanotubes (HNTs) in water were conducted. Three polymers with different charges-anionic (pectin), neutral (hydroxypropyl cellulose), and cationic (chitosan)-were chosen. The thermodynamic parameters for the adsorption of polymers onto the HNT surface were determined by isothermal titration calorimetry (ITC). The experimental data were interpreted based on a Langmuir adsorption model. The standard variations in free energy, enthalpy, and entropy of the process were obtained and discussed. Turbidimetry was used to evaluate the stability of functionalized nanoparticles in water. The ζ-potential clarified the surface charge properties of functionalized nanotubes upon polymer adsorption. The interaction of modified nanotubes with polymers led to the formation of a colloidal system with tunable stability and surface properties, which offers different perspectives on new applications of these dispersions, such as carriers for substances to be released in response to external stimuli 
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700 1 |a Cavallaro, Giuseppe  |e verfasserin  |4 aut 
700 1 |a Lazzara, Giuseppe  |e verfasserin  |4 aut 
700 1 |a Milioto, Stefana  |e verfasserin  |4 aut 
700 1 |a Parisi, Filippo  |e verfasserin  |4 aut 
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