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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201606860
|2 doi
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|a pubmed24n0898.xml
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|a (DE-627)NLM269580859
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|a (NLM)28266753
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Soto, Fernando A
|e verfasserin
|4 aut
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| 245 |
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|a Tuning the Solid Electrolyte Interphase for Selective Li- and Na-Ion Storage in Hard Carbon
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 18.07.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Solid-electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li- and Na-ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li- or Na-based electrolyte, and that ionic transport can be kinetically controlled. Selective Li- and Na-based SEI membranes are produced using Li- or Na-based electrolytes, respectively. The Na-based SEI allows easy transport of Li ions, while the Li-based SEI shuts off Na-ion transport. Na-ion storage can be manipulated by tuning the SEI layer with film-forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g-1 ; ≈ 1/10 of the normal capacity (250 mAh g-1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion-selective conductors using electrochemical approaches
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|a Journal Article
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|a Li-ion batteries
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|a Na-ion batteries
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|a selective ion transfer
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|a solid-electrolyte interphase
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|a Yan, Pengfei
|e verfasserin
|4 aut
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1 |
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|a Engelhard, Mark H
|e verfasserin
|4 aut
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1 |
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|a Marzouk, Asma
|e verfasserin
|4 aut
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1 |
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|a Wang, Chongmin
|e verfasserin
|4 aut
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|a Xu, Guiliang
|e verfasserin
|4 aut
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1 |
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|a Chen, Zonghai
|e verfasserin
|4 aut
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1 |
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|a Amine, Khalil
|e verfasserin
|4 aut
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1 |
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|a Liu, Jun
|e verfasserin
|4 aut
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|a Sprenkle, Vincent L
|e verfasserin
|4 aut
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|a El-Mellouhi, Fedwa
|e verfasserin
|4 aut
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|a Balbuena, Perla B
|e verfasserin
|4 aut
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| 700 |
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|a Li, Xiaolin
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 18 vom: 19. Mai
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:29
|g year:2017
|g number:18
|g day:19
|g month:05
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|u http://dx.doi.org/10.1002/adma.201606860
|3 Volltext
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