Feasibility of Cathode Surface Coating Technology for High-Energy Lithium-ion and Beyond-Lithium-ion Batteries

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 48 vom: 27. Dez.
1. Verfasser: Kalluri, Sujith (VerfasserIn)
Weitere Verfasser: Yoon, Moonsu, Jo, Minki, Liu, Hua Kun, Dou, Shi Xue, Cho, Jaephil, Guo, Zaiping
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Review beyond-lithium-ion batteries cathode materials energy density lithium-ion batteries surface coating technology
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520 |a Cathode material degradation during cycling is one of the key obstacles to upgrading lithium-ion and beyond-lithium-ion batteries for high-energy and varied-temperature applications. Herein, we highlight recent progress in material surface-coating as the foremost solution to resist the surface phase-transitions and cracking in cathode particles in mono-valent (Li, Na, K) and multi-valent (Mg, Ca, Al) ion batteries under high-voltage and varied-temperature conditions. Importantly, we shed light on the future of materials surface-coating technology with possible research directions. In this regard, we provide our viewpoint on a novel hybrid surface-coating strategy, which has been successfully evaluated in LiCoO2 -based-Li-ion cells under adverse conditions with industrial specifications for customer-demanding applications. The proposed coating strategy includes a first surface-coating of the as-prepared cathode powders (by sol-gel) and then an ultra-thin ceramic-oxide coating on their electrodes (by atomic-layer deposition). What makes it appealing for industry applications is that such a coating strategy can effectively maintain the integrity of materials under electro-mechanical stress, at the cathode particle and electrode- levels. Furthermore, it leads to improved energy-density and voltage retention at 4.55 V and 45 °C with highly loaded electrodes (≈24 mg.cm-2 ). Finally, the development of this coating technology for beyond-lithium-ion batteries could be a major research challenge, but one that is viable 
650 4 |a Journal Article 
650 4 |a Review 
650 4 |a beyond-lithium-ion batteries 
650 4 |a cathode materials 
650 4 |a energy density 
650 4 |a lithium-ion batteries 
650 4 |a surface coating technology 
700 1 |a Yoon, Moonsu  |e verfasserin  |4 aut 
700 1 |a Jo, Minki  |e verfasserin  |4 aut 
700 1 |a Liu, Hua Kun  |e verfasserin  |4 aut 
700 1 |a Dou, Shi Xue  |e verfasserin  |4 aut 
700 1 |a Cho, Jaephil  |e verfasserin  |4 aut 
700 1 |a Guo, Zaiping  |e verfasserin  |4 aut 
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773 1 8 |g volume:29  |g year:2017  |g number:48  |g day:27  |g month:12 
856 4 0 |u http://dx.doi.org/10.1002/adma.201605807  |3 Volltext 
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