C3 N-A 2D Crystalline, Hole-Free, Tunable-Narrow-Bandgap Semiconductor with Ferromagnetic Properties

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 16 vom: 05. Apr.
1. Verfasser: Yang, Siwei (VerfasserIn)
Weitere Verfasser: Li, Wei, Ye, Caichao, Wang, Gang, Tian, He, Zhu, Chong, He, Peng, Ding, Guqiao, Xie, Xiaoming, Liu, Yang, Lifshitz, Yeshayahu, Lee, Shuit-Tong, Kang, Zhenhui, Jiang, Mianheng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D materials carbon ferromagnetic properties semiconductors
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520 |a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 
520 |a Graphene has initiated intensive research efforts on 2D crystalline materials due to its extraordinary set of properties and the resulting host of possible applications. Here the authors report on the controllable large-scale synthesis of C3 N, a 2D crystalline, hole-free extension of graphene, its structural characterization, and some of its unique properties. C3 N is fabricated by polymerization of 2,3-diaminophenazine. It consists of a 2D honeycomb lattice with a homogeneous distribution of nitrogen atoms, where both N and C atoms show a D6h -symmetry. C3 N is a semiconductor with an indirect bandgap of 0.39 eV that can be tuned to cover the entire visible range by fabrication of quantum dots with different diameters. Back-gated field-effect transistors made of single-layer C3 N display an on-off current ratio reaching 5.5 × 1010 . Surprisingly, C3 N exhibits a ferromagnetic order at low temperatures (<96 K) when doped with hydrogen. This new member of the graphene family opens the door for both fundamental basic research and possible future applications 
650 4 |a Journal Article 
650 4 |a 2D materials 
650 4 |a carbon 
650 4 |a ferromagnetic properties 
650 4 |a semiconductors 
700 1 |a Li, Wei  |e verfasserin  |4 aut 
700 1 |a Ye, Caichao  |e verfasserin  |4 aut 
700 1 |a Wang, Gang  |e verfasserin  |4 aut 
700 1 |a Tian, He  |e verfasserin  |4 aut 
700 1 |a Zhu, Chong  |e verfasserin  |4 aut 
700 1 |a He, Peng  |e verfasserin  |4 aut 
700 1 |a Ding, Guqiao  |e verfasserin  |4 aut 
700 1 |a Xie, Xiaoming  |e verfasserin  |4 aut 
700 1 |a Liu, Yang  |e verfasserin  |4 aut 
700 1 |a Lifshitz, Yeshayahu  |e verfasserin  |4 aut 
700 1 |a Lee, Shuit-Tong  |e verfasserin  |4 aut 
700 1 |a Kang, Zhenhui  |e verfasserin  |4 aut 
700 1 |a Jiang, Mianheng  |e verfasserin  |4 aut 
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