Co-pyrolysis characteristics of municipal sewage sludge and hazelnut shell by TG-DTG-MS and residue analysis
Copyright © 2017 Elsevier Ltd. All rights reserved.
Veröffentlicht in: | Waste management (New York, N.Y.). - 1999. - 62(2017) vom: 15. Apr., Seite 91-100 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | Waste management (New York, N.Y.) |
Schlagworte: | Journal Article Bio-char Co-pyrolysis Hazelnut shell Municipal sewage sludge TG-DTG-MS Sewage |
Zusammenfassung: | Copyright © 2017 Elsevier Ltd. All rights reserved. Co-pyrolysis characteristics of municipal sewage sludge and hazelnut shell blend have been studied in this work. The behavior of co-pyrolysis was researched by a method of multi-heating rates and different blend ratios to analyze thermal decomposition stages. The experimental data of the blended samples in TG-DTG plots were compared with calculated data to investigate the interactions during co-pyrolysis. The bio-chars investigated by SEM and FTIR spectra were used to examine the physical and chemical changes. The results showed there are four thermal decomposition stages during co-pyrolysis, with hydrocarbon transforming to gas evolution in the second and the third stages. The inhibitive interaction occurred between 260 and 400°C and the accelerative interaction occurred between 450 and 900°C during co-pyrolysis. The activation energy of the blended sample was 51.97-178.84kJ/mol in the second stage and 207.04-630.73kJ/mol in the third stage calculated by DAEM |
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Beschreibung: | Date Completed 02.08.2017 Date Revised 02.12.2018 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1879-2456 |
DOI: | 10.1016/j.wasman.2017.02.012 |