Photoinduced Plasticity in Cross-Linked Liquid Crystalline Networks

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 17 vom: 05. Mai
1. Verfasser: McBride, Matthew K (VerfasserIn)
Weitere Verfasser: Hendrikx, Matthew, Liu, Danqing, Worrell, Brady T, Broer, Dirk J, Bowman, Christopher N
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article adaptable networks liquid crystalline networks photoinduced plasticity reversible-addition fragmentation chain-transfer
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520 |a Photoactivated reversible addition fragmentation chain transfer (RAFT)-based dynamic covalent chemistry is incorporated into liquid crystalline networks (LCNs) to facilitate spatiotemporal control of alignment, domain structure, and birefringence. The RAFT-based bond exchange process, which leads to stress relaxation, is used in a variety of conditions, to enable the LCN to achieve a near-equilibrium structure and orientation upon irradiation. Once formed, and in the absence of subsequent triggering of the RAFT process, the (dis)order in the LCN and its associated birefringence are evidenced at all temperatures. Using this approach, the birefringence, including the formation of spatially patterned birefringent elements and surface-active topographical features, is selectively tuned by adjusting the light dose, temperature, and cross-linking density 
650 4 |a Journal Article 
650 4 |a adaptable networks 
650 4 |a liquid crystalline networks 
650 4 |a photoinduced plasticity 
650 4 |a reversible-addition fragmentation chain-transfer 
700 1 |a Hendrikx, Matthew  |e verfasserin  |4 aut 
700 1 |a Liu, Danqing  |e verfasserin  |4 aut 
700 1 |a Worrell, Brady T  |e verfasserin  |4 aut 
700 1 |a Broer, Dirk J  |e verfasserin  |4 aut 
700 1 |a Bowman, Christopher N  |e verfasserin  |4 aut 
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