Confined Amorphous Red Phosphorus in MOF-Derived N-Doped Microporous Carbon as a Superior Anode for Sodium-Ion Battery
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 16 vom: 11. Apr. |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article N-doping ZIF-8 microporous carbon red phosphorus sodium-ion batteries |
Zusammenfassung: | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Red phosphorus (P) has attracted intense attention as promising anode material for high-energy density sodium-ion batteries (NIBs), owing to its high sodium storage theoretical capacity (2595 mAh g-1 ). Nevertheless, natural insulating property and large volume variation of red P during cycling result in extremely low electrochemical activity, leading to poor electrochemical performance. Herein, the authors demonstrate a rational strategy to improve sodium storage performance of red P by confining nanosized amorphous red P into zeolitic imidazolate framework-8 (ZIF-8) -derived nitrogen-doped microporous carbon matrix (denoted as PN-MPC). When used as anode for NIBs, the P@N-MPC composite displays a high reversible specific capacity of ≈600 mAh g-1 at 0.15 A g-1 and improved rate capacity (≈450 mAh g-1 at 1 A g-1 after 1000 cycles with an extremely low capacity fading rate of 0.02% per cycle). The superior sodium storage performance of the P@N-MPC is mainly attributed to the novel structure. The N-doped porous carbon with sub-1 nm micropore facilitates the rapid diffusion of organic electrolyte ions and improves the conductivity of the encapsulated red P. Furthermore, the porous carbon matrix can buffer the volume change of red P during repeat sodiation/desodiation process, keeping the structure intact after long cycle life |
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Beschreibung: | Date Completed 18.07.2018 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201605820 |