Exceptionally High Ionic Conductivity in Na3 P0.62 As0.38 S4 with Improved Moisture Stability for Solid-State Sodium-Ion Batteries

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 16 vom: 18. Apr.
1. Verfasser: Yu, Zhaoxin (VerfasserIn)
Weitere Verfasser: Shang, Shun-Li, Seo, Joo-Hwan, Wang, Daiwei, Luo, Xiangyi, Huang, Qingquan, Chen, Shuru, Lu, Jun, Li, Xiaolin, Liu, Zi-Kui, Wang, Donghai
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article all-solid-state battery first-principles calculations sodium-ion conductor solid-state electrolyte sulfide
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520 |a A Na-ion solid-state electrolyte, Na3 P0.62 As0.38 S4 , is developed with an exceptionally high conductivity of 1.46 mS cm-1 at 25 °C and enhanced moisture stability. Dual effects of alloying element As (lattice expansion and a weaker AsS bond strength) are responsible for the superior conductivity. Improved moisture stability is regulated by shifting low-energy moisture reactions to high-energy ones due to As 
650 4 |a Journal Article 
650 4 |a all-solid-state battery 
650 4 |a first-principles calculations 
650 4 |a sodium-ion conductor 
650 4 |a solid-state electrolyte 
650 4 |a sulfide 
700 1 |a Shang, Shun-Li  |e verfasserin  |4 aut 
700 1 |a Seo, Joo-Hwan  |e verfasserin  |4 aut 
700 1 |a Wang, Daiwei  |e verfasserin  |4 aut 
700 1 |a Luo, Xiangyi  |e verfasserin  |4 aut 
700 1 |a Huang, Qingquan  |e verfasserin  |4 aut 
700 1 |a Chen, Shuru  |e verfasserin  |4 aut 
700 1 |a Lu, Jun  |e verfasserin  |4 aut 
700 1 |a Li, Xiaolin  |e verfasserin  |4 aut 
700 1 |a Liu, Zi-Kui  |e verfasserin  |4 aut 
700 1 |a Wang, Donghai  |e verfasserin  |4 aut 
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