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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.7b00326
|2 doi
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|a pubmed24n0896.xml
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|a (DE-627)NLM268905126
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|a (NLM)28191979
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Draper, Emily R
|e verfasserin
|4 aut
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|a Nonlinear Effects in Multicomponent Supramolecular Hydrogels
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 11.05.2018
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|a Date Revised 11.05.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Multicomponent low molecular weight gels are useful for a range of applications. However, when mixing two components, both of which can independently form a gel, there are many potential scenarios. There is a limited understanding as to how to control and direct the assembly. Here, we focus on a pH-triggered two-component system. At high pH, colloidal structures are formed, and there is a degree of mixing of the two gelators. As the pH is decreased, there is a complex situation, where one gelator directs the assembly in a "sergeants and soldiers" manner. The second gelator is not fully incorporated, and the remainder forms an independent network. The result is that there is a nonlinear dependence on the final mechanical properties of the gels, with the storage or loss modulus being very dependent on the absolute ratio of the two components in the system
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Wallace, Matthew
|e verfasserin
|4 aut
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|a Schweins, Ralf
|e verfasserin
|4 aut
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1 |
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|a Poole, Robert J
|e verfasserin
|4 aut
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1 |
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|a Adams, Dave J
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 33(2017), 9 vom: 07. März, Seite 2387-2395
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:33
|g year:2017
|g number:9
|g day:07
|g month:03
|g pages:2387-2395
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|u http://dx.doi.org/10.1021/acs.langmuir.7b00326
|3 Volltext
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|d 33
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