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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.4583
|2 doi
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|a eng
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|a Osipov, Alexander K
|e verfasserin
|4 aut
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|a Study of E/Z isomerization of (arylamino)methylidenefuran-2(3H)-ones by 1 H, 13 C, 15 N spectroscopy and DFT calculations in different solvents
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|c 2017
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 05.03.2018
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|a Date Revised 05.03.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Copyright © 2017 John Wiley & Sons, Ltd.
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|a The structure and configuration of the series of previously unknown arylaminomethylidenefuran-2(3H)-ones have been determined in solution by 1 H, 13 C, 15 N nuclear magnetic resonance spectroscopy including two-dimensional experiments such as 1 H─1 H COSY, dqCOSY, 1 H─13 C HSQC, 1 H─13 C HMBC. It was found that synthesized substances exist as an equilibrium mixture of E- and Z-enamines in solution. It was established on the basis of density functional theory calculations that the exchange between the two push-pull enamines is a simple rotation around an exocyclic partial double bond that depends on the effect of the solvents. Copyright © 2017 John Wiley & Sons, Ltd
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|a Journal Article
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|a E/Z isomerization
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|a arylaminomethylene derivatives of furanones
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|a condensation
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|a configuration
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|a furan-2(3H)-ones
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|a push-pull olefins
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|a triethyl orthoformate
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1 |
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|a Anis'kov, Alexander A
|e verfasserin
|4 aut
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1 |
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|a Grinev, Vyacheslav S
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yegorova, Alevtina Yu
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 55(2017), 8 vom: 15. Aug., Seite 730-737
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnas
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| 773 |
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|g volume:55
|g year:2017
|g number:8
|g day:15
|g month:08
|g pages:730-737
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|u http://dx.doi.org/10.1002/mrc.4583
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