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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.6b04410
|2 doi
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|a eng
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| 100 |
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|a Sun, Ya-Sen
|e verfasserin
|4 aut
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|a Tailoring Carbon Nanostructure with Diverse and Tunable Morphology by the Pyrolysis of Self-Assembled Lamellar Nanodomains of a Block Copolymer
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|c 2017
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 07.05.2018
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|a Date Revised 07.05.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The pyrolysis of a block copolymer thin film, the free surface of which was in contact with air or a capping layer of SiO2, produced four carbon nanostructures. Thin films of a diblock copolymer having perpendicularly oriented lamellar nanodomains served as carbon and nitrogen precursors. Before pyrolysis, the lamellar nanodomains were cross-linked with UV irradiation under nitrogen gas (UVIN). Without a capping layer, pyrolysis caused a structural transformation from lamellar nanodomains to short carbon nanowires or to dropletlike nanocarbons in a row via Rayleigh instability, depending on the duration of pyrolysis. When capped with a layer of SiO2 followed by pyrolysis, the lamellar nanodomains were converted to pod-like, spaghetti-like, or long worm-like carbon nanostructures. These carbon nanostructures were driven by controlling the surface or interface tension and the residual yield of solid carbonaceous species
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Huang, Wei-Hua
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lin, Chien-Fu
|e verfasserin
|4 aut
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| 700 |
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|a Cheng, Shao-Liang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 33(2017), 8 vom: 28. Feb., Seite 2003-2010
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|x 1520-5827
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|g volume:33
|g year:2017
|g number:8
|g day:28
|g month:02
|g pages:2003-2010
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|u http://dx.doi.org/10.1021/acs.langmuir.6b04410
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