Hole Mobility and Electron Injection Properties of D-A Conjugated Copolymers with Fluorinated Phenylene Acceptor Units

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 7 vom: 30. Feb.
1. Verfasser: Wang, Ming (VerfasserIn)
Weitere Verfasser: Ford, Michael J, Lill, Alexander T, Phan, Hung, Nguyen, Thuc-Quyen, Bazan, Guillermo C
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article donor-acceptor conjugated copolymers electron injection fluorinated phenylenes organic field-effect transistors stability
Beschreibung
Zusammenfassung:© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A novel wide-gap conjugated polymer PhF2,5 (Eg = 1.9 eV) is designed to contain alternating cyclopentadithiophene and difluorophenylene unit with the goal of favoring unipolar organic field effect transistor characteristics. The higher lowest unoccupied molecular orbital energy of PhF2,5 increases the barrier to electron injection, leading to unipolar transport and higher on/off ratios, without sacrificing desirable high hole mobilities
Beschreibung:Date Completed 18.07.2018
Date Revised 01.10.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201603830