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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.6b03456
|2 doi
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|a pubmed24n0892.xml
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|a eng
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|a Zubir, Moondra
|e verfasserin
|4 aut
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|a Micropore Formation of [Zn2(Oxac) (Taz)2]·(H2O)2.5 via CO2 Adsorption
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|c 2017
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|a Text
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|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 13.04.2018
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|a Date Revised 13.04.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a As-synthesized [Zn2(Oxac) (Taz)2]·(H2O)2.5, referred to as ZOTW2.5, was prepared from aqueous methanol solutions of Zn5(CO3)2(OH)6 and two kinds of ligands of 1,2,4-triazole (Taz) and oxalic acid (Oxac) at 453 K for 12 h. The crystal structure was determined by the Rietveld method. As-synthesized ZOTW2.5 was pretreated at 383 K and 1 mPa for tpt h, ZOTWx(tpth). ZOTWx(≥3h) showed a type I adsorption isotherm for N2 at 77 K having a saturation amount (Vs) of 180 mg/g, but that pretreated shortly showed only 1/10 in Vs. CO2 was adsorbed at 303 K in sigmoid on nonporous ZOTWx(≤2h) and in Langmuir-type on ZOTWx(≥3h) to reach the adsorption amount of 120 mg/g at 700 Torr. N2 adsorption on ZOTWx(≤2h)deCO2, degassed after CO2 adsorption on ZOTWx(≤2h), was promoted 5-fold from 180 mg/g on ZOTWx(tpth) and ZOTWx(≥3h)deCO2 up to ca. 1000 mg/g. The interaction of CO2 and H2O molecules in micropores may lead to a new route for micropore formation
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Hamasaki, Atom
|e verfasserin
|4 aut
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|a Iiyama, Taku
|e verfasserin
|4 aut
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|a Ohta, Akira
|e verfasserin
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|a Ohki, Hiroshi
|e verfasserin
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|a Ozeki, Sumio
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 33(2017), 3 vom: 24. Jan., Seite 680-684
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:33
|g year:2017
|g number:3
|g day:24
|g month:01
|g pages:680-684
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|u http://dx.doi.org/10.1021/acs.langmuir.6b03456
|3 Volltext
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