Formation of hybrid guanidine-stabilized bis(μ-oxo)dicopper cores in solution Electronic and steric perturbations

Formation of hybrid guanidine-stabilized bis(μ-oxo)dicopper cores in solution : Electronic and steric perturbations

A series of new hybrid peralkylated-amine-guanidine ligands based on a 1,3-propanediamine backbone and their Cu-O2 chemistry is reported. The copper(I) complexes react readily with O2 at low temperatures in aprotic solvents with weakly coordinating anions to form exclusively bis(μ-oxo) dicopper spec...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:European journal of inorganic chemistry. - 1998. - 2015(2015), 32 vom: 19. Nov., Seite 5426-5436
1. Verfasser: Herres-Pawlis, Sonja (VerfasserIn)
Weitere Verfasser: Haase, Roxana, Verma, Pratik, Hoffmann, Alexander, Kang, Peng, Stack, T Daniel P
Format: Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:European journal of inorganic chemistry
Schlagworte:Journal Article Copper Density Functional Theory Dioxygen Guanidine Ligands UV/Vis-Spectroscopy