Structure beyond pair correlations : X-ray cross-correlation from colloidal crystals

The results of an X-ray cross-correlation analysis (XCCA) study on hard-sphere colloidal crystals and glasses are presented. The article shows that cross-correlation functions can be used to extract structural information beyond the static structure factor in such systems. In particular, the powder...

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Bibliographische Detailangaben
Veröffentlicht in:Journal of applied crystallography. - 1998. - 49(2016), Pt 6 vom: 01. Dez., Seite 2046-2052
1. Verfasser: Lehmkühler, Felix (VerfasserIn)
Weitere Verfasser: Fischer, Birgit, Müller, Leonard, Ruta, Beatrice, Grübel, Gerhard
Format: Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Journal of applied crystallography
Schlagworte:Journal Article X-ray cross-correlation analysis coherent X-ray scattering colloidal crystals small-angle X-ray scattering
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520 |a The results of an X-ray cross-correlation analysis (XCCA) study on hard-sphere colloidal crystals and glasses are presented. The article shows that cross-correlation functions can be used to extract structural information beyond the static structure factor in such systems. In particular, the powder average can be overcome by accessing the crystals' unit-cell structure. In this case, the results suggest that the crystal is of face-centered cubic type. It is demonstrated that XCCA is a valuable tool for X-ray crystallography, in particular for studies on colloidal systems. These are typically characterized by a rather poor crystalline quality due to size polydispersity and limitations in experimental resolution because of the small q values probed. Furthermore, nontrivial correlations are observed that allow a more detailed insight into crystal structures beyond conventional crystallography, especially to extend knowledge in structure formation processes and phase transitions 
650 4 |a Journal Article 
650 4 |a X-ray cross-correlation analysis 
650 4 |a coherent X-ray scattering 
650 4 |a colloidal crystals 
650 4 |a small-angle X-ray scattering 
700 1 |a Fischer, Birgit  |e verfasserin  |4 aut 
700 1 |a Müller, Leonard  |e verfasserin  |4 aut 
700 1 |a Ruta, Beatrice  |e verfasserin  |4 aut 
700 1 |a Grübel, Gerhard  |e verfasserin  |4 aut 
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