Molecularly Tuned Free Volume of Vapor Cross-Linked 6FDA-Durene/ZIF-71 MMMs for H2 /CO2 Separation at 150 °C
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 4 vom: 21. Jan. |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article cross-linker chain motion high temperature hydrogen separation mixed matrix membranes tunable free volume vapor cross-linking |
| Zusammenfassung: | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The H2 /CO2 separation properties of di/triamine vapor cross-linked mixed matrix membranes with molecularly tuned free-volume at 150 °C are reported. Free-volume is molecularly tuned by altering the degree of chain-motion using cross-linkers with different chain lengths. A more restricted degree of chain-motion is achieved in the cross-linked network and the resultant membrane has a higher H2 /CO2 selectivity at 150 °C |
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| Beschreibung: | Date Completed 18.07.2018 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201603833 |