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231224s2017 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.4538
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|a eng
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|a Dunn, Anna L
|e verfasserin
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|a Progress toward reaction monitoring at variable temperatures
|b a new stopped-flow NMR probe design
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|c 2017
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|a Text
|b txt
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|a ƒaComputermedien
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|a Date Completed 05.04.2018
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|a Date Revised 05.04.2018
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Copyright © 2016 John Wiley & Sons, Ltd.
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|a A stopped-flow NMR probe is described that enables fast flow rates, short transfer times, and equilibration of the reactant magnetization and temperature prior to reaction. The capabilities of the probe are demonstrated by monitoring the polymerization of lactide as catalyzed by the air-sensitive catalyst 1,3-dimesitylimidazol-2-ylidene (IMes) over the temperature range of -30 to 40 °C. The incorporation of stopped-flow capabilities into an NMR probe permits the rich information content of NMR to be accessed during the first few seconds of a fast reaction. Copyright © 2016 John Wiley & Sons, Ltd
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|a Journal Article
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|a kinetics
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|a reaction monitoring
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|a stopped-flow NMR
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|a 1,3-dimesitylimidazolin-2-ylidene
|2 NLM
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| 650 |
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|a Imidazoles
|2 NLM
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| 650 |
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|a Polyesters
|2 NLM
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|a poly(lactide)
|2 NLM
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|a 459TN2L5F5
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1 |
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|a Landis, Clark R
|e verfasserin
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|t Magnetic resonance in chemistry : MRC
|d 1985
|g 55(2017), 4 vom: 07. Apr., Seite 329-336
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|g pages:329-336
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