Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes Evidence for an Insertion Mechanism

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes : Evidence for an Insertion Mechanism

We have prepared and structurally characterized a new class of Fe(II) PNP pincer hydride complexes [Fe(PNP-iPr)(H)(CO)(L)] n (L = Br-, CH3CN, pyridine, PMe3, SCN-, CO, BH4-; n = 0, +1) based on the 2,6-diaminopyridine scaffold where the PiPr2 moieties of the PNP ligand are connected to the pyridine...

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Veröffentlicht in:Organometallics. - 1998. - 33(2014), 23 vom: 08. Dez., Seite 6905-6914
1. Verfasser: Gorgas, Nikolaus (VerfasserIn)
Weitere Verfasser: Stöger, Berthold, Veiros, Luis F, Pittenauer, Ernst, Allmaier, Günter, Kirchner, Karl
Format: Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Organometallics
Schlagworte:Journal Article