Synthesis and Reactivity of Four- and Five-Coordinate Low-Spin Cobalt(II) PCP Pincer Complexes and Some Nickel(II) Analogues
Anhydrous CoCl2 or [NiCl2(DME)] reacts with the ligand PCPMe-iPr (1) in the presence of nBuLi to afford the 15e and 16e square planar complexes [Co(PCPMe-iPr)Cl] (2) and [Ni(PCPMe-iPr)Cl] (3), respectively. Complex 2 is a paramagnetic d7 low-spin complex, which is a useful precursor for a series of...
| Publié dans: | Organometallics. - 1998. - 33(2014), 21 vom: 10. Nov., Seite 6132-6140 |
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| Auteur principal: | |
| Autres auteurs: | , , , , , , |
| Format: | Article |
| Langue: | English |
| Publié: |
2014
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| Accès à la collection: | Organometallics |
| Sujets: | Journal Article |