Naphthalenediimide Polymers with Finely Tuned In-Chain π-Conjugation : Electronic Structure, Film Microstructure, and Charge Transport Properties

© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 28(2016), 41 vom: 30. Nov., Seite 9169-9174
1. Verfasser: Erdmann, Tim (VerfasserIn)
Weitere Verfasser: Fabiano, Simone, Milián-Medina, Begoña, Hanifi, David, Chen, Zhihua, Berggren, Magnus, Gierschner, Johannes, Salleo, Alberto, Kiriy, Anton, Voit, Brigitte, Facchetti, Antonio
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article charge transport conjugation naphthalenediimide polymer transistors
Beschreibung
Zusammenfassung:© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Naphthalenediimide-based random copolymers (PNDI-TVTx) with different π-conjugated dithienylvinylene (TVT) versus π-nonconjugated dithienylethane (TET) unit ratios (x = 100→0%) are investigated. The PNDI-TVTx-transistor electron/hole mobilities are affected differently, a result rationalized by molecular orbital topologies and energies, with hole mobility vanishing but electron mobility decreasing only by ≈2.5 times when going from x = 100% to 40%
Beschreibung:Date Completed 17.07.2018
Date Revised 30.09.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201602923