Ammonia nitrogen removal from acetylene purification wastewater from a PVC plant by struvite precipitation

Acetylene purification wastewater (APW) usually contains high concentrations of ammonia nitrogen (NH4-N), which is generated during the production of acetylene in a polyvinylchloride manufacturing plant. In this study, a struvite precipitation method was selected to remove NH4-N from the APW. Labora...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 74(2016), 2 vom: 01., Seite 508-15
1. Verfasser: Zhu, Lei (VerfasserIn)
Weitere Verfasser: Dong, DeMing, Hua, XiuYi, Guo, ZhiYong, Liang, DaPeng
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Industrial Waste Phosphates Waste Water Ammonia 7664-41-7 Polyvinyl Chloride 9002-86-2 Struvite AW3EJL1462 mehr... Magnesium I38ZP9992A Acetylene OC7TV75O83
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520 |a Acetylene purification wastewater (APW) usually contains high concentrations of ammonia nitrogen (NH4-N), which is generated during the production of acetylene in a polyvinylchloride manufacturing plant. In this study, a struvite precipitation method was selected to remove NH4-N from the APW. Laboratory-scale batch experiments were performed to investigate the effects of the initial APW pH, phosphate (PO4(3-)) concentration, magnesium (Mg(2+)) concentration, and sources of PO4(3-) and Mg(2+) on NH4-N removal. The results indicated that the initial APW pH had a significant effect on the removal of NH4-N, while the other factors had relatively minor effect. The NH4-N could be effectively removed at an optimum initial APW pH of 9.5, when Na2HPO4·12H2O and MgSO4·7H2O were both applied to NH4-N at a ratio of 1.2. Under these conditions, the efficiency of removal of NH4-N, total nitrogen and chemical oxygen demand were 85%, 84% and 18%, respectively. The X-ray diffraction analysis indicated that the precipitates were dominated by struvite. The scanning electron microscopy analysis of the precipitates showed a typical morphology of stick-like and prismatic crystals with coarse surface. The energy dispersive spectroscopy analysis indicated that the precipitates contained P, O, Mg and Ca 
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650 7 |a Polyvinyl Chloride  |2 NLM 
650 7 |a 9002-86-2  |2 NLM 
650 7 |a Struvite  |2 NLM 
650 7 |a AW3EJL1462  |2 NLM 
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700 1 |a Dong, DeMing  |e verfasserin  |4 aut 
700 1 |a Hua, XiuYi  |e verfasserin  |4 aut 
700 1 |a Guo, ZhiYong  |e verfasserin  |4 aut 
700 1 |a Liang, DaPeng  |e verfasserin  |4 aut 
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