Effect of competing amines on the removal of tetramethylammonium hydroxide from solution using ion exchange

Tetramethylammonium hydroxide (TMAH, TMA(+)) has been widely used as the photoresist developer in semiconductor and thin film transistor liquid crystal display manufacturing. In this study, TMAH-containing wastewater was treated by ion exchange method. Strong acid cation exchange resin was used. A k...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 74(2016), 2 vom: 01., Seite 466-72
1. Verfasser: Citraningrum, H M (VerfasserIn)
Weitere Verfasser: Liu, Jhy-Chern
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Amines Cation Exchange Resins Diethylamines Ethylamines Quaternary Ammonium Compounds Waste Water diethylamine B035PIS86W tetramethylammonium mehr... H0W55235FC triethylamine VOU728O6AY ethylamine YG6MGA6AT5
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520 |a Tetramethylammonium hydroxide (TMAH, TMA(+)) has been widely used as the photoresist developer in semiconductor and thin film transistor liquid crystal display manufacturing. In this study, TMAH-containing wastewater was treated by ion exchange method. Strong acid cation exchange resin was used. A kinetics study revealed that the ion exchange reaction reached equilibrium within 20 min and it could be described by a pseudo-second-order model. To assess the effects of competing ions, wastewater was spiked with three different amines, namely ethylamine (EA(+)), diethylamine (DEA(+)), and triethylamine (TEA(+)). TMAH uptake decreased when in the presence of amines, and it decreased in the order EA(+) < DEA(+) < TEA(+). It could be attributed to different proton affinity (PA) and the strength of affinity between amine molecules and resin matrix, as found from the ab initio calculation values and Langmuir isotherm parameters. However, the interaction energy between sulphonic acid groups and interfering amines in solution using density functional theory (DFT) calculation resulted in a different trend compared with that of PA. The difference might be caused by stabilization of amines by resin matrix and different molecular structures 
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650 7 |a triethylamine  |2 NLM 
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650 7 |a ethylamine  |2 NLM 
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700 1 |a Liu, Jhy-Chern  |e verfasserin  |4 aut 
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